Episode 88,

We are coming to the end of the torture scene and Mr White comes to the rescue of Bond by dispatching Le Chiffre. We’re covering minutes 113 & 114. 

From the Blu Ray commentary:

Each of these were done, 3 masters, 2 shot master, a single on Mikkelsen, all done as complete takes. I kept Daniel’s eyes in the dark, because he was under pressure. The actors had to do it 4-5 times, sometimes they prefer not to do it too many times. Our opinion is that we’ll keep going to get it as gooas we can, because you’ll never get a perfect take. The last shot of the scene, was quite hard. We had a 2 second focus ball from background to foreground.

When Bond says ‘The Big Picture’ it’s a call back from his earlier meeting with M when she says

‘We’re trying to find out how an entire network is run and you give us one Bombmaker, hardly the big picture wouldn’t you say?’